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Surface Chemistry

Adsorption, catalysis, colloids and emulsions

Key Concepts

  • Adsorption: accumulation of substance on surface (adsorbate on adsorbent)
  • Physisorption: weak van der Waals forces; chemisorption: chemical bonds
  • Colloids: dispersed particles 1–1000 nm in size; show Tyndall effect
  • Coagulation: colloidal particles aggregate and settle
  • Catalysis: catalyst provides alternative pathway with lower activation energy

Important Formulae

Freundlich adsorption isotherm x/m = kP^(1/n), n ≥ 1
Langmuir adsorption isotherm x/m = abP / (1 + bP)

Quick Tips

  • Physisorption increases at low T; chemisorption increases at high T (up to a limit).
  • Sols: solid dispersed in liquid; gels: liquid dispersed in solid; emulsion: liquid in liquid.
  • Hardy-Schulze rule: higher valency of coagulating ion → more effective coagulation.

Sample Practice Questions

  1. Peptisation means:

    • Adding more solvent
    • Converting precipitate back to colloidal state by adding electrolyte
    • Coagulating a colloid
    • Filtering a colloid
    Show answer

    Answer: Converting precipitate back to colloidal state by adding electrolyte

  2. Lyophilic colloids (e.g. gelatin in water) are:

    • Unstable and irreversible
    • Stable and reversible
    • Always negative
    • Same as emulsions
    Show answer

    Answer: Stable and reversible

  3. Chemisorption is:

    • Reversible and weak
    • Irreversible and involves chemical bond formation
    • Same as physisorption
    • Only at high pressures
    Show answer

    Answer: Irreversible and involves chemical bond formation

  4. Tyndall effect is the scattering of light by:

    • True solutions
    • Colloidal particles
    • Pure solvents
    • Ions
    Show answer

    Answer: Colloidal particles

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Practice Questions

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Frequently Asked Questions

What are the key concepts in Surface Chemistry for NEET?

Adsorption: accumulation of substance on surface (adsorbate on adsorbent); Physisorption: weak van der Waals forces; chemisorption: chemical bonds; Colloids: dispersed particles 1–1000 nm in size; show Tyndall effect; Coagulation: colloidal particles aggregate and settle; Catalysis: catalyst provides alternative pathway with lower activation energy.

Which formulae are important for Surface Chemistry in NEET?

Freundlich adsorption isotherm: x/m = kP^(1/n), n ≥ 1; Langmuir adsorption isotherm: x/m = abP / (1 + bP).

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