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Atomic Structure

Bohr model, quantum numbers, electronic configuration

Key Concepts

  • Bohr model: electrons in circular orbits; quantised energy and angular momentum
  • Quantum numbers: n (principal), l (azimuthal), m_l (magnetic), m_s (spin)
  • Aufbau principle: fill lowest energy orbitals first
  • Hund's rule: maximum unpaired electrons in degenerate orbitals
  • Pauli exclusion principle: no two electrons can have identical quantum numbers

Important Formulae

Bohr energy (hydrogen) E_n = −13.6/n² eV
de Broglie wavelength λ = h/mv
Heisenberg uncertainty Δx · Δp ≥ h/4π
Orbital angular momentum L = √[l(l+1)] · h/2π
Max electrons in shell n 2n²

Quick Tips

  • l ranges from 0 to n−1; m_l ranges from −l to +l; m_s = +½ or −½.
  • Order of filling: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p … (n+l rule).
  • Cr is [Ar]3d⁵4s¹ and Cu is [Ar]3d¹⁰4s¹ — exceptions due to extra stability of half-filled/fully-filled d-orbitals.

Sample Practice Questions

  1. Rutherford's gold foil experiment showed that:

    • Electrons are embedded in a sphere
    • The nucleus is small, dense and positively charged
    • Atom has no nucleus
    • Electrons revolve in fixed orbits
    Show answer

    Answer: The nucleus is small, dense and positively charged

  2. The maximum number of orbitals in n=3 shell:

    • 3
    • 6
    • 9
    • 12
    Show answer

    Answer: 9

  3. The electron having highest energy in ²³Na (sodium):

    • 2p⁶
    • 3s¹
    • 2s²
    • 1s²
    Show answer

    Answer: 3s¹

  4. The shape of a p orbital is:

    • Spherical
    • Dumbbell
    • Double dumbbell
    • Clover leaf
    Show answer

    Answer: Dumbbell

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Practice Questions

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Frequently Asked Questions

What are the key concepts in Atomic Structure for NEET?

Bohr model: electrons in circular orbits; quantised energy and angular momentum; Quantum numbers: n (principal), l (azimuthal), m_l (magnetic), m_s (spin); Aufbau principle: fill lowest energy orbitals first; Hund's rule: maximum unpaired electrons in degenerate orbitals; Pauli exclusion principle: no two electrons can have identical quantum numbers.

Which formulae are important for Atomic Structure in NEET?

Bohr energy (hydrogen): E_n = −13.6/n² eV; de Broglie wavelength: λ = h/mv; Heisenberg uncertainty: Δx · Δp ≥ h/4π; Orbital angular momentum: L = √[l(l+1)] · h/2π; Max electrons in shell n: 2n².

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