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Chemical Bonding

Ionic, covalent, metallic bonds, VSEPR, hybridisation

Key Concepts

  • Ionic bonding: transfer of electrons; forms between metal and non-metal
  • Covalent bonding: sharing of electrons; VSEPR predicts geometry
  • Hybridisation: sp (linear), sp² (trigonal planar), sp³ (tetrahedral)
  • Molecular orbital theory: bonding and antibonding orbitals
  • Hydrogen bonding: strong dipole–dipole involving N, O, or F

Important Formulae

Bond order (MO theory) BO = (bonding e⁻ − antibonding e⁻) / 2
Formal charge FC = V − N − B/2 (V=valence e⁻, N=non-bonding, B=bonding)
Dipole moment μ = q × d

Quick Tips

  • Lone pairs cause greater repulsion than bonding pairs — they reduce bond angle (H₂O: 104.5°, NH₃: 107°).
  • Bond order > 0 means stable molecule; BO = 0 means molecule does not exist (e.g. He₂).
  • Resonance structures: actual bond lengths are intermediate; benzene is the classic example.

Sample Practice Questions

  1. Lattice energy of an ionic compound depends on:

    • Mass of ions only
    • Charge and size of ions
    • Temperature only
    • Solvent polarity
    Show answer

    Answer: Charge and size of ions

  2. Bond order from MO theory = :

    • (Bonding e⁻ + Antibonding e⁻) / 2
    • (Bonding e⁻ − Antibonding e⁻) / 2
    • Total electrons / 2
    • Bonding e⁻ / 2
    Show answer

    Answer: (Bonding e⁻ − Antibonding e⁻) / 2

  3. The shape of PCl₅ is:

    • Square pyramidal
    • Trigonal bipyramidal
    • Octahedral
    • Tetrahedral
    Show answer

    Answer: Trigonal bipyramidal

  4. Hybridization of carbon in CH₄ is:

    • sp
    • sp²
    • sp³
    • dsp²
    Show answer

    Answer: sp³

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Practice Questions

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Frequently Asked Questions

What are the key concepts in Chemical Bonding for NEET?

Ionic bonding: transfer of electrons; forms between metal and non-metal; Covalent bonding: sharing of electrons; VSEPR predicts geometry; Hybridisation: sp (linear), sp² (trigonal planar), sp³ (tetrahedral); Molecular orbital theory: bonding and antibonding orbitals; Hydrogen bonding: strong dipole–dipole involving N, O, or F.

Which formulae are important for Chemical Bonding in NEET?

Bond order (MO theory): BO = (bonding e⁻ − antibonding e⁻) / 2; Formal charge: FC = V − N − B/2 (V=valence e⁻, N=non-bonding, B=bonding); Dipole moment: μ = q × d.

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