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Redox Reactions

Oxidation-reduction, oxidation states, balancing redox

Key Concepts

  • Oxidation: loss of electrons / increase in oxidation state
  • Reduction: gain of electrons / decrease in oxidation state
  • OIL RIG: Oxidation Is Loss, Reduction Is Gain
  • Oxidising agent: gets reduced; reducing agent: gets oxidised
  • Disproportionation: same element is simultaneously oxidised and reduced

Important Formulae

Balancing by half-reaction (acidic) Add H₂O to balance O, H⁺ to balance H, then balance charge
Oxidation state of O Usually −2 (except peroxides −1, OF₂ +2)
Oxidation state of H Usually +1 (except metal hydrides −1)

Quick Tips

  • F₂ is the strongest oxidising agent; Li is the strongest reducing agent.
  • In MnO₄⁻: Mn is +7; in Cr₂O₇²⁻: Cr is +6 — both are strong oxidisers in acidic medium.
  • Sum of oxidation states in a neutral compound = 0; in an ion = ion charge.

Sample Practice Questions

  1. In the half-reaction: MnO₄⁻ + 8H⁺ + 5e⁻ → Mn²⁺ + 4H₂O, MnO₄⁻ is:

    • Reducing agent
    • Oxidising agent
    • Both
    • Neither
    Show answer

    Answer: Oxidising agent

  2. Balancing redox equations in acidic medium: H⁺ and __ are used to balance charge:

    • OH⁻
    • H₂O
    • O₂
    • H₂
    Show answer

    Answer: H₂O

  3. Equivalent weight of KMnO₄ in acidic medium (M = 158, n-factor = 5):

    • 158
    • 79
    • 31.6
    • 52.7
    Show answer

    Answer: 31.6

  4. In electrochemical cells, oxidation occurs at:

    • Cathode
    • Anode
    • Both electrodes
    • Salt bridge
    Show answer

    Answer: Anode

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Practice Questions

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Frequently Asked Questions

What are the key concepts in Redox Reactions for NEET?

Oxidation: loss of electrons / increase in oxidation state; Reduction: gain of electrons / decrease in oxidation state; OIL RIG: Oxidation Is Loss, Reduction Is Gain; Oxidising agent: gets reduced; reducing agent: gets oxidised; Disproportionation: same element is simultaneously oxidised and reduced.

Which formulae are important for Redox Reactions in NEET?

Balancing by half-reaction (acidic): Add H₂O to balance O, H⁺ to balance H, then balance charge; Oxidation state of O: Usually −2 (except peroxides −1, OF₂ +2); Oxidation state of H: Usually +1 (except metal hydrides −1).

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